A jar '$\mathrm{P}' is filled with gas having pressure, volume and temperature \mathrm{P}, \mathrm{V}, \mathrm{T} respectively. Another gas jar Q filled with a gas having pressure 2 \mathrm{P}, volume \frac{\mathrm{V}}{4} and temperature 2 \mathrm{~T}. The ratio of the number of molecules in jar \mathrm{P} to those in jar Q$ is